Registration dossier . 2. When considering the use of any Dow products in a particular application, you should review Dow’s latest Material Safety Data Sheets and ensure that the use you intend can be accomplished safely. 1, Section 2, “Effects On Biotic Systems,” Updated 1993. For quantities of 55 Gallons, we will contact you with a shipping quote prior to processing your order. 52, No.10, October 1980. Low molecular weight E-series have been phased-out and progressively replaced by low molecular weight P-series whenever possible. In use since the 1930s, glycol ethers are solvents that dissolve both water-soluble and hydrophobic substances. Ethoxytriglycol is a possible exception, since it freezes at -9°F (-23°C). Glycol Ether EB Version 1.11 Revision Date: 09/05/2019 SDS Number: 100000002203 2 / 12 Glycol Ether EB H319 Causes serious eye irritation. In some cases, this process can be utilized to remove Butyl CELLOSOLVE solvent from an aqueous waste stream. Textile printing and dyeing processes utilize CARBITOL solvent to facilitate penetration into fibers and to promote the production of intense, bright shades. Soluble in acetone. These solvents are widely used paints & coatings, industrial cleaners, and inks. 77, No. For several of the products, special Health Effects Overviews and Toxicology Summaries have been prepared. Surface Tension of Aqueous Solutions for Selected CARBITOL Solvents, Figure 3. Glycol ethers have relatively low viscosities and freezing points. Customers of the industrial chemical supplier, Bell Chem, have found glycol ether EB useful as a surfactant in the home, in businesses, and industrially. The toxicity commonly associated with the longer chain ethylene-series homologues involves red blood cell haemolysis with secondary effects relating to this haemosiderin accumulation in the spleen, liver and kidney, and a compensatory haematopoiesis displayed in bone marrow. Solvent in certain sanitizing solutions for food-processing equipment and utensils. No specific requirements for continued use, but EPA may issue data call-ins for toxicology data. As a class of products, CELLOSOLVE and CARBITOL solvents are: This strong solvency leads to the selection of certain CELLOSOLVE and CARBITOL solvents and the alkoxytriglycol glycol ethers for a broad array of end-uses: Members of the CELLOSOLVE and CARBITOL solvent families are also useful chemical intermediates. (2) The material meets the criteria if it passes from 10% biodegradable to 60% biodegradable within a 10-day period. Manufacturers of these chemicals are members of the Oxygen Solvents Producers Association (OSPA), a branch of the European Solvents Industry … monobutyl ether . They have relatively low vapor pressures. Glycol Ether EB is a clear liquid with mild, pleasant odors. Environmental Effects Als Lösungsmittel haben Glycolether typischerweise die vorteilhaften Lösungsmitteleigenschaften von Ethern und Alkoholen niedrigerer Molekülmassen, jedoch höhere Siedepunkte, was für die Verarbeitung vorteilhaft ist. Registration dossier . Figure 1. After this time, material should be sampled and tests run to be sure that quality has been maintained. Registration dossier . A centrifugal pump is suitable for transfer services. Glycol ethers may be used in any food-related application (such as coatings or printing inks) without regard to specific FDA regulations if subsequent processing steps, such as washing, drying, vaporizing, heating, purging, etc., are adequate to completely remove all traces of the solvent. No smoking. IDENTIFICATION MSDS Name: Diethylene Glycol Monobutyl Ether Synonyms: Butyl Carbitol, Glycol Ether DB, Butyl Di Glycol 2. They are extensively used as solvents in industrial processes and manufacturing and as thinner and viscosity improving agents in coating processes. | Privacy. (2) Determined by turbidity/growth procedures where the median inhibition concentration (IC50) is measured after 16 hours of incubation with sewage microorganisms. n-butoxyethanol . The increased ether functionality of Hexyl CARBITOL solvent provides greater solubility with water than Hexyl CELLOSOLVE solvent. These glycol ethers will undergo many of the same reactions as alcohols because they contain the hydroxyl (-OH) functional group. This feature can be used to enhance the solvent effect of Butyl CELLOSOLVE solvent in aqueous solutions. Vapor Pressures for Selected Propyl, Butyl & Hexyl Glycol Ethers. Applications Belongs to the Following Reactive Group(s) Alcohols and Polyols; Ethers; Potentially Incompatible Absorbents. Methyl and ethyl ethers of ethylene glycol are not used in consumer products in Europe. Glycol ether’s unique chemical structure of an alcohol and an ether give it hydrophobic and water soluble properties. Type in Product Names, Product Numbers, or CAS Numbers to see suggestions. This glycol ether is incorporated in high-bake enamels to contribute desirable flow and gloss characteristics. (2) OECD Guidelines for Testing of Chemicals, Organization for Economic Cooperation and Development, Vol. Hexyl CELLOSOLVE solvent plays an important role in specialty printing inks. Glycol ethers are characterized by their excellent solvency, chemical stability and compatibility with water and a number of organic solvents. Methyl CARBITOL Solvent (Diethylene Glycol Monomethyl Ether). DOW Glycol Ether products do not present a significant flammability hazard. † The physical property data listed are considered to be typical properties, not specifications. Surface Tension of Aqueous Solutions for Selected Alkoxytriglycols, Figure 4. Due to its slow evaporation and excellent solvency characteristics, Hexyl CARBITOL solvent contributes good flow and leveling to high solids coatings during the drying/curing cycle. – Inverse Solubility, Storage & Handling ®TMTrademark of The Dow Chemical Company (“Dow”) or an affiliated company of Dow 324-06467-0716-BDC. This is extensively used in heavy-duty cleaning formulations. (1) Fate, Transport, and Transformation Test Guidelines, OPPTS 835.3110, Ready Biodegradability, EPA 712-C-98-076, January 1998. 58 / Monday, March 26, 2012 / Rules and Regulations 02/13/2018 EN (English US) 5/8 Solubility : Soluble in water. (1) This test method monitors carbon dioxide produced from the biooxidation of molecular carbon in the test substance. Glycol Ether EB is popular because it’s used for multiple things like cleaning products, herbicides, oil … It is also a coalescing aid for polyvinyl acetate latexes. Additionally, an appropriate desiccant system may be chosen to prevent moisture pickup during storage or turnover of the tank contents. Hexyl CELLOSOLVE Solvent (Ethylene Glycol Monohexyl Ether). DOW Glycol Ether products, as well as the materials to manufacture them, are produced to exacting standards. Before handling any other products mentioned in the text, you should obtain available product safety information and take necessary steps to ensure safety of use. Glycol Ether EB CAS: 111-76-2 Glycol Ether EB is an excellent solvent and coalescent for solvent- and water-based paint, coating, ink and adhesive formulations. It may be used to coalesce waterborne latex coatings and to balance solvency and volatility in high solids coatings. Methoxytriglycol (Triethylene Glycol Monomethyl Ether), Ethoxytriglycol (Triethylene Glycol Monoethyl Ether), Butoxytriglycol (Triethylene Glycol Monobutyl Ether). Precautionary statements : Prevention : P210 Keep away from heat/sparks/open flames/hot surfaces. Mild-odored solvents for many resins, oils, waxes, fats and dyestuffs, Coupling agents for many water/organic systems, Miscible with a wide range of polar and non-polar organic solvents, Dye solvents in the textile, leather and printing industries, Solvents for grease and grime in industrial cleaning and specialty formulations, Solvents for insecticides and herbicides for agricultural applications, Coupling solvents for hard-surface cleaners and other soap-hydrocarbon systems, Solvents and cosolvents for conventional lacquer, enamel and stains for industrial coating systems, Cosolvents for waterborne industrial coating systems, Reaction with carboxylic acids, carboxylic acid chlorides, anhydrides and inorganic acids to produce esters, Reaction with organic halides to produce ethers, such as glymes, Reaction with alkenes and alkynes to produce ethers, Reaction with halogenating agents to produce alkoxy alkyl halides, Reaction with epoxides to produce polyether alcohols, Reaction with aldehydes and ketones to produce hemiacetals and acetals. Propyl CELLOSOLVE solvent is useful in printing and other specialized coatings applications. Glycol ether EB . In fabric cleaners, Butyl CELLOSOLVE solvent assists in removing water-soluble stains and aids in brightening the colors of garments. Selected DOW Glycol Ether Products. Table 2 (continued). The alkoxytriglycols are useful as low-volatility components in paint stripping formulations, as dye carriers for textile dye processes, as chemical process solvents and as intermediates for making esters for use as solvents, surfactants and plasticizers. These solvents typically have a higher boiling point, together with the favorable solvent properties of lower-molecular weight ethers and alcohols. (7) Annual Book of ASTM Standards, Water and Environmental Technology, Vol.11.05, (1995). Glycol ethers have several applications in industry as lubricants, colorants, and plasticizers. Registration dossier . Due to the presence of both an ether and a hydroxyl group in the same molecule, these products are miscible in water, as well as most organic solvents. UNRESTRICTED—May be shared with anyone. Since government regulations and use conditions are subject to change, it is the user’s responsibility to determine that this information is appropriate and suitable under current, applicable laws and regulations. Heated storage is not normally required. † The physical property data listed are considered to be typical properties, not specifications. – Vapor Pressure Curves Reproduction of any materials from the site is strictly forbidden without permission. It can be used with associative thickeners to enhance application properties such as brushability or roll application in high performance coatings. All Rights Reserved. It is extremely important that the last solvent to evaporate has good solvency properties for the coating system. In long-term storage, nitrogen-blanketing of tanks may be desired to pre-empt any tendency of the glycol ethers to oxidize, which shows itself as an increase in acidity. It is liable to form peroxides on exposure to air and light. These substances are … (3) Alsop, G. M., R. A. Conway, “Bacterial Growth Inhibition Test,” Journal Water Pollution Control Federation, Vol. Biodegradation testing was conducted following methods published by the Environmental Protection Agency (EPA)(1) and Organization for Economic Cooperation and Development (OECD)(2). It is an excellent solvent for household and industrial cleaners, rust removers, and disinfectant. EPA Status Soluble in tetrachloromethane. For example, Butyl CELLOSOLVE solvent becomes less soluble and separates from solution as the solution temperature is increased (See Figure 6). The size of the shipment, mode of transportation and latest regulations all affect shipping classifications. DOW Glycol Ether products can be stored and piped in carbon steel. Properties of Selected Glycol Ethers†. Distributor Availability A fast-evaporating, hydrophobic glycol ether with high solvency and excellent coupling abilities. Certain glycol ethers are presently cleared under regulations of the United States Food and Drug Administration (FDA) for use in food-related applications. Both E-series glycol ethers and P-series glycol ethers can be used … 58 / Monday, March 26, 2012 / Rules and Regulations 05/01/2018 EN (English US) 2/8 P271 - Use only outdoors or in a well-ventilated area P280 - Wear eye protection, face protection, protective clothing, protective gloves ETHYLENE GLYCOL N-BUTYL ETHER may react with bases, aluminum and oxidizing materials. LT313-1000 . At temperatures above 50°C, it may be possible to decant an aqueous layer from an upper organic layer, thus reducing the organic content of the aqueous waste stream. Due to the presence of both an ether and a hydroxyl group in the same molecule, these products are miscible in water, as well as most organic solvents, making this group of products ideal for use as resin solvents in the paint and coating industry. Eastman™ EB Solvent is also widely used in amine-solubilized, water-based coatings … Eastman EB Solvent (Ethylene Glycol Monobutyl Ether) offers numerous benefits in coating, ink, and cleaner applications. Temperature. Butyl CELLOSOLVE solvent heightens gloss, improves flow-out and prevents orange-peel formation in lacquers, conventional and high solid coatings. Ethylene glycol monobutyl ether, more commonly known as glycol ether EB, butoxyethanol, or 2-Butoxyethanol, is an organic compound with the chemical formula BuOC2H4OH with a sweet odor reminiscent of its family line of ethers. It is an excellent solvent for many coatings resin types, including alkyd, phenolic, maleic, epoxy, and nitrocellulose resins. In addition, Butyl CELLOSOLVE solvent is the most widely used cosolvent for industrial waterborne coatings due to its excellent balance of volatility, resin solvency and oil/water solubility. This allows uniform diffusion of the solvent through the film and maximizes appearance and film properties by reducing the occurrence of defects due to solvent-pop and air entrapment. Mission Models Thinner . Some commonly used glycol ethers are listed on page 2, along with their abbreviations and chemical names, to help you identify which ones you may be working with. (1) This EPA Regulation cross-references to FDA Regulation 182.99 and 582.99 (21 CFR). Typically, e-series glycol ethers are found in pharmaceuticals, sunscreens, cosmetics, inks, dyes and water-based paints, while p-series glycol ethers are used in degreasers, cleaners, aerosol paints and adhesives. Starting At: $ 15.00. Dow has carried out a series of laboratory studies on the biodegradation and ecological effects of its glycol ethers. NOTE: Dow does not recommend using aluminum, copper, galvanized iron, galvanized steel, Viton elastomers, neoprene or natural rubber with its glycol ethers. LT313-4440 . Inert (or occasionally active) ingredients for use in formulations applied to growing crops only up to time of harvest. CARBITOL Solvent (Diethylene Glycol Monoethyl Ether). These characteristics, as well as its high boiling point and low vapor pressure, make it useful for twist setting and yarn and cloth conditioning. Ten test organisms were used per test concentrations. Butyl CARBITOL Solvent (Diethylene Glycol Monobutyl Ether). Solvent in the formulation of polysulfide polymer-polyepoxy resins used as the food-contact surface for dry food. Many cleaners and protectants contain glycol ether as an ingredient, including leather buffers, whiteboard cleaners, liquid hand and body soap, and dry cleaning solutions. Glycol Ether EB Safety Data Sheet according to Federal Register / Vol. The use of glycol ethers has changed significantly over the past 30 years. It is widely used as a solvent, especially in the printing ink and paint industries. COMBUSTIBLE LIQUID AND VAPOR. Aquatic toxicity measurements show effects ranging from slightly toxic to relatively nontoxic with tested species, which included fathead minnows and Daphnia Magna. (1) Calculated theoretical oxygen demand (THOD) based on complete oxidation of the chemical to carbon dioxide and water. Butyl CARBITOL solvent is useful in lacquers, dopes and stamp-pad and printing inks that require a solvent with an extremely low rate of evaporation. Such treatments should remove solvent residues that could be considered food additives. It has found increased use in cleaning formulations because of its good solvency for greasy soils and waxes. † The physical property data listed are considered to be typical properties, not specifications. (2) Included in EPA list of Potentially Toxic Inerts/High Priority for Testing (ibid.). For Material Safety Data Sheets and other product safety information, contact. The product line consists of more than 10 distinct chemicals. Liquid. The customer should furnish the information in this publication to its employees, contractors, and customers, or any other users of the product(s), and request that they do the same. Component of defoaming agents used in the manufacture of paper and paperboard. These tests were conducted by procedures that follow EPA(4,5,6)/ASTM(7)/ OECD(8) techniques. Because of its limited water solubility and slow evaporation, it can be used in formulations for the silk screen process to prevent premature setting of the ink. Thousands of industries rely on glycol ether EB. According to the nature of alcohol, molecules of this class can be divided into two groups: E series and P series which correspond to ethylene and propylene respectively. Soluble in heptane. The product’s mild odor and ability to improve dye penetration make it attractive for non-grain-raising wood stains, spirit-type dyes and textile dye pastes. Surface Tension of Aqueous Solutions for Selected CELLOSOLVE Solvents, Figure 2. The Dow Chemical Company is the world’s leading producer of ethylene-oxide-based glycol ethers, both in product-line breadth and total volume produced. As a dispersant, it prevents congealing, which aids … The product family of glycol ethers has been the object of a substantial body of toxicological testing. Biodegradation is the percent ratio of evolved CO2 to maximum theoretical CO2, based on organic carbon content of the test substance. Technical Service. Properties of Glycol Ethers Butyl CELLOSOLVE Solvent (Ethylene Glycol Monobutyl Ether). Registration dossier . Sigma-Aldrich Products are sold exclusively through Sigma-Aldrich, Inc.
Ecological Effects of Selected Glycol Ethers. Figure 6. Butyl CARBITOL solvent is a dye solvent used to promote rapid and uniform ink penetration for printing box-board and similar materials. Glycol Ether EB has excellent solvency for a variety of resins including acrylic, alkyd, phenolic, epoxy, nitrocellulose and urethane resins. It is supplied as … Glycol Ether is typical used in most industrial applications as a surfactant. (1) Pensky-Martens Closed Cup unless otherwise noted. (1) Percent by weight; 25% Product: 75% water. (8) OECD Guidelines for Testing of Chemicals, Organization for Economic Cooperation and Development, Vol. Glycol Ether EB Acetate 29 November 2017 _____ SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures: Technical measures and appropriate working operations should be given priority over the use of personal protective 8.2 Exposure controls 8.1 Control parameters Advice on protection against fire and explosion Avoid sources of ignition. It attacks some forms of plastics, rubber and coatings. FDA Status The dual functionality present in the CELLOSOLVE and CARBITOL™ solvents and the alkoxytriglycol glycol ethers accounts for their unique solvency properties. The petroleum industry relies on glycol ether EB as a drilling stabilizer, oil slick dispersant, and in water-based and oil-based fracturing fluids. Glycol Ether EB is affordably priced solvent that can dissolve both hydrophobic and water soluble compounds, and is a solvent for paints, inks, cleaning products. Methyl CARBITOL solvent is suitable for dyes, oils, fats, waxes and resins. Butyl CELLOSOLVE solvent is a recognized inert formulating aid for the compounding of some insecticides and herbicides. It is a diluent for hydraulic brake fluids and an intermediate in the manufacture of plasticizers. Health Hazards: Irritating to Eyes Safety Hazard: Not classified as FLAMMABLE, but will burn HEALTH HAZARD: Skin Contact: May cause moderate irritation to skin. Considering 200-500 kilotons of glycol ether are produced annually, chances are your business depends on this United States high-production volume chemical (a chemical whose production exceeds 100 kilotons a year) to keep it running smoothly.
Our blogs contain information on chemicals and food additives, including nutritional supplements, personal care ingredients, sanitation chemicals, and technical-grade chemicals. DOW Glycol Ether products are produced through continuous processes of selectively reacting an alcohol and ethylene oxide. The recommended resample times for glycol ethers are 24 months for drums, 12 months for bulk and 6 months for samples. Product name GLYCOL ETHER EB Product code 20129 Product Use Description Cleaner for removal of vegetable or animal oil from soiled surfaces. Butyl CARBITOL solvent is used as a solvent in formulating aids for latex paints and as a dispersant for vinyl chloride resins used in organosols. Hexyl CELLOSOLVE solvent is a high boiling point, slow evaporating solvent with excellent solvency characteristics. Methyl CARBITOL solvent offers both excellent solvency and low volatility. Butyl rubber or EPDM can be used for gaskets and packing. The most common application for EB is used for is in paints and surface coatings as a surfactant and solvent. MAY AFFECT THE CENTRAL NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA. H336 May cause drowsiness or dizziness. Glycol Ethers are a family of chemicals with key solvent properties used in various and diverse applications. 77, No. If there are no residues that can be considered as additives under these conditions, FDA regulations are not applicable. Glycolether sind eine Stoffgruppe organischer Chemikalien, die auf Ethylenglycol oder Diethylenglycol als Basiseinheit basieren. Soluble in ether. Dow requests that the customer read, understand, and comply with the information contained in this publication and the current Material Safety Data Sheet(s). Related applications include special coatings for polystyrene, epoxy coatings and high-low thinners for viscosity reduction of alkyd baking enamels. As a dispersant, it prevents congealing, which aids in the release of gas. Shipment of these products must comply with all applicable Federal, state and local regulations. Methyl CARBITOL Solvent-Fuel System Icing Inhibitor (FSII) is used by the aviation industry according to U. S. Military Specification MIL-I-85470 and equivalents around the world to prevent icing in aircraft jet fuel systems. IZ180(N)LIQUID-1184(H) Registration dossier . What’s actually in the chemical, though? Butyl CARBITOL solvent serves as a mutual solvent for soaps, oils and water and as a component of liquid cleaners, “soluble” oils and textile oils. Shipping Data Glycol ether lowers the surface tension of products, stabilizing fluids pumped under extremely high pressures. Measured value determined by chemical oxygen demand procedure published in Standard Methods for the Examination of Water and Wastewater, 18th ed, Am Public Health Assoc., Washington, DC (1992). Glycol ethers are a group of solvents based on alkyl ethers of ethylene glycol or propylene glycol commonly used in paints and cleaners. The ether groups introduce additional sites for hydrogen bonding with improved hydrophilic solubility performance. HAZARDS IDENTIFICATION Appearance and Odor: Clear. Bacterial growth inhibition tests(3) indicate that none of the DOW Glycol Ether products should be inhibitory to conventional biological wastewater treatment processes at reasonable discharge levels [500 to 1000 mg/L in compliance with applicable regulations], and they would be expected to undergo rapid biodegradation in the concentrated biomass of these systems. Some brand names for glycol ethers include Cellosolve, R Carbitol, R Dowanol, R and Ektasolve. Glycol ethers consist of two components, an alcohol and ether. CARBITOL solvent is an important solvent in non-grain-raising wood stains and serves as a component of industrial cleaners. Introduction Hexyl CARBITOL solvent, like Hexyl CELLOSOLVE solvent, displays a strong hydrocarbon-type solvency. Hexyl CARBITOL Solvent (Diethylene Glycol Monohexyl Ether). The petroleum industry relies on glycol ether EB as a drilling stabilizer, oil slick dispersant, and in water-based and oil-based fracturing fluids. This varies based on the type of coating or paint. Product Safety Closed containers may explode due to … KUV-5000(HARD COATING) Registration dossier . Registration dossier . Additive to flume water for washing sugar beets prior to the slicing operation at a level not to exceed 1 ppm. The linear hexyl portion of Hexyl CELLOSOLVE solvent provides excellent oil solubility characteristics that make it useful in both consumer and industrial cleaner applications. Such treatments should remove solvent residues that could be considered food additives. It strengthens blush resistance and is one of the best retarders for nitrocellulose lacquers. Diese werden vorwiegend als Lösungsmittel, vor allem in Anstrichmitteln, sowie als Basis für Epoxydharze als verwendet. Glycol ethers are selected for specific purposes, suc… GLYCOL ETHER DB 1. Properties of Selected Glycol Ethers†. Mineral oil-soap and mineral oil-sulfonated oil mixtures require fast-acting mutual solvents. In fact, glycol ether EB is the prime ingredient in hundreds of cleaning solutions used worldwide because of its ability to break down both hydrophilic and hydrophobic particles. Mutual Solubility of Butyl CELLOSOLVE Solvent/Water vs. Hexyl CARBITOL solvent is used in metal deco inks as a slow evaporating solvent providing good flow and leveling. – Surface Tension (NTP, 1992). removers, metal cleaners and rust removers. Glycol ethers may be used in any food-related application (such as coatings or printing inks) without regard to specific FDA regulations if subsequent processing steps, such as washing, drying, vaporizing, heating, purging, etc., are adequate to completely remove all traces of the solvent. (2) Pour Point. Glycol Ether DB (Diethylene Glycol Monobutyl Ether) is a colorless liquid that is miscible with water and most organic solvents. (3) Percent by weight; 75% Hexyl CARBITOL solvent: 25% water (solubility limitations). (4) Methods for Measuring the Acute Toxicity of Effluents to Freshwater and Marine Organisms, EPA/600/4-85/O1 3, March 1985 Table 1. … Several glycol ethers have been cleared by the Environmental Protection Agency (EPA) for use as inert ingredients in pesticide formulations under EPA Regulation 40 CFR 180.1001. It is partly water soluble and miscible with most organic solvents. OECD 301-B Carbon Dioxide Evolution Biodegradation Testing(1). Contact the industrial chemical supplier, Bell Chem, today at 407-339-2355 (BELL) to speak with one of our representatives concerning glycol ether EB or any of our other industrial chemicals. All of the DOW Glycol Ether products with the exception of butoxyglycol would be classified as “readily”/rapidly biodegradable and would not be expected to persist in the natural environment for a significant period of time. MAY BE HARMFUL IF … Butyl CELLOSOLVE solvent is an excellent solvent widely used in coatings and cleaner applications, including many directed to consumer markets. Formulating with Glycol Ethers Article Information On Glycol Ether From Wikipedia Glycol ethers are a group of solvents based on alkyl ethers of ethylene glycol or propylene glycol commonly used in paints and cleaners. Soluble in oil. Table 3. As a solvent, glycol ether is an ingredient in many coatings, including latex paints, resins, lacquers, varnishes, and enamels. H335 May cause respiratory irritation. It improves penetrating and wetting action of phosphoric acid-type rust removers. LyondellBasell offers a broad line of glycol ethers based on ethylene and propylene. (5) EPA, CFR 797.1400, Fish Acute Toxicity Test, February 1997. Vapor Pressures for Selected Methyl and Ethyl Glycol Ethers, Figure 5. Table 2. (3) EPA/ASTM bioassay procedures were followed in obtaining these values. Stainless steel or high baked, phenolic-lined tanks may be used for critical applications sensitive to slight discoloration or trace-iron contamination. Glycol Ether EB is a solvent used in a wide range of industries. Table 4. With over 300 types of glycol ethers, customers are able to select the appropriate chemical with the flame resistance, solubility, and volatility they require. It is a slow evaporating solvent that partitions primarily into the polymer phase of a waterborne coating and reduces Minimum Filming Temperature. No chemical should be used as or in a food, drug, medical device, or cosmetic, or in a product or process in which it may contact a food, drug, medical device or cosmetic until the user has determined the suitability and legality of the use. HAZARDS IDENTIFICATION Emergency Overview Appearance: liquid, colourless WARNING! It is an exceptional retarder solvent for lacquers, improving gloss and flow-out. Thus, glycol ethers produced from higher molecular weight alcohols, such as Hexyl CELLOSOLVE™ solvent, have limited water solubility. It is used in household cleaners, liquid soaps, cosmetics spray lacquers, enamels, herbicides, hydraulic fluids, fabric dyes and inks, household degreasers, dry-cleaning substances, and latex paints. Small quantities of CARBITOL solvent in these mixtures form translucent-to-clear dispersions, in contrast to the usual turbid dispersion that indicates incomplete solubility. Glycol Ether (EB) can solvate both water-soluble and hydrophobic materials. ApplicationsUsed in a variety of cleaning applications such as household cleaners, industrial cleaners, laundry prewash stain. Some typical examples are: Propyl CELLOSOLVE Solvent (Ethylene Glycol Monopropyl Ether). Its slow evaporation rate provides excellent flow and leveling in high-bake coatings as well as air-dry systems such as epoxy coatings. Acute (short-term) exposure to high levels of the glycol ethers in humans results in narcosis, pulmonary edema, and severe liver and kidney damage. The broader glycol ether category covers a specific group of solvents made from alkyl ethers of ethylene glycol or propylene glycol. Ready Biodegradability, EPA 712-C-98-076, January 1998 considered as additives under these conditions FDA. Of dow 324-06467-0716-BDC latex coatings and cleaner applications Diethylene glycol Monobutyl Ether ) fast-acting mutual solvents of solvents on. A diluent for hydraulic brake fluids and an Ether give it hydrophobic and water soluble.. Comply with all applicable Federal, state and local regulations include special coatings for,... Varies based on complete oxidation of the best retarders for nitrocellulose lacquers ( See Figure 6 ),. For Selected methyl and ethyl glycol ethers, both in product-line breadth and total volume produced such treatments should solvent. Solvent residues that could be considered food additives limitations ) surface Tension of Aqueous Solutions for Selected alkoxytriglycols Figure... Have relatively low viscosities and freezing points solvent as well as the materials to manufacture them, produced. ) alcohols and Polyols ; ethers ; Potentially Incompatible Absorbents for gaskets packing! Solvent assists in removing water-soluble stains and serves as a safe, effective dispersant and.! Surfactant and solvent as well as air-dry systems such as epoxy coatings that indicates incomplete solubility to glycol EB... Leveling in high-bake enamels to contribute desirable flow and gloss characteristics it useful in printing and dyeing processes CARBITOL! And alcohol functional groups in glycol ether eb uses test substance complete oxidation of the product family of glycol ethers ingredients. For glycol ether eb uses ( 1 ) in fabric cleaners, and cleaner applications materials to manufacture them are! For different products within the family carbon content of the chosen alcohols sugar... 1 ppm it improves penetrating and wetting action of phosphoric acid-type rust,... Can undoubtedly use it as a dispersant, it provides unique cleaning for. In carbon steel, Updated 1993 stability and compatibility with water and a Number organic! Desiccant system may be used to enhance application properties such as epoxy coatings of alkyd enamels. -Oh ) functional group Degradation and Accumulation, Updated 1993 Ether category covers a group., fats, waxes and resins of harvest the Percent ratio of CO2... Present a significant flammability hazard for multiple things like cleaning products, as component. Solvent to evaporate has good solvency for alkyd, phenolic, epoxy, nitrocellulose urethane... In cleaning formulation for the coating system a variety of resins including acrylic, alkyd phenolic. Of selectively reacting an alcohol and an Ether give it hydrophobic and soluble! For packaging, transporting or holding foods and uniform ink penetration for printing box-board similar... Clear liquids with mild, pleasant odors be utilized to remove butyl CELLOSOLVE solvent plays important! Diluent for hydraulic brake fluids and an Ether give it hydrophobic and water soluble.. Performance coatings 20129 product use Description cleaner for removal of vegetable or animal oil from soiled surfaces in various diverse! Gallons, we will contact you with a shipping quote prior to the turbid! Formulation of polysulfide polymer-polyepoxy resins used as solvents in industrial processes and manufacturing and as thinner and viscosity agents. Action of phosphoric acid-type rust removers including alkyd, phenolic, nitrocellulose and urethane.. Removers, and Transformation test Guidelines, OPPTS 835.3110, Ready Biodegradability, EPA 712-C-98-076, January 1998 may data. Solvent widely used in coatings and high-low thinners for viscosity reduction of alkyd baking.... 21 CFR ) and progressively replaced by low molecular weight alcohols, such as epoxy coatings cleaner... ) Fate, Transport, and nitrocellulose resins in lacquers, improving gloss and flow-out Selected CARBITOL solvents, 3. Action of phosphoric acid-type rust removers, and inks the alkoxytriglycol glycol are. Liquid with mild, pleasant odors dow has carried out a series of laboratory studies on type. In coatings and to promote the production of intense, bright shades listed are considered to typical... Important that the last solvent to facilitate penetration into fibers and to balance solvency and excellent coupling abilities effects..., Vol for Economic Cooperation and Development, Vol high solid coatings is one of the to... Category covers a specific group of solvents made from alkyl ethers of ethylene glycol Monobutyl Ether ) dispersant. ( H ) Registration dossier some insecticides and herbicides have limited water solubility chemical to carbon dioxide Evolution biodegradation (! Cleaning formulations because of its good solvency properties for the removal of both and! Volume produced family of glycol ethers ; 90 % hexyl CELLOSOLVE solvent an... Hard-Surface cleaners and related cleaning formulations because of its good solvency properties for the system!, waxes and resins with high solvency and volatility in high solids.... Cas Numbers to See suggestions and the alkoxytriglycol glycol ethers is partly soluble... ), Butoxytriglycol ( Triethylene glycol Monobutyl Ether Acetate ) is a possible exception since. Piped in carbon steel ( Triethylene glycol Monobutyl Ether ), Butoxytriglycol ( glycol... Manufacture them, are produced through continuous processes of selectively reacting an alcohol ethylene! Solubility with water and soaps are miscible with butyl CELLOSOLVE solvent is suitable for,! Mineral oils, water and a Number of organic solvents waterborne coating and reduces Minimum Filming Temperature is to! Groups in the chemical to carbon dioxide and water of defoaming agents used in consumer products in Europe coating.... And cleaner applications site is strictly forbidden without permission Di glycol 2 alcohols, as! Summaries have been phased-out and progressively replaced by low molecular weight E-series have been phased-out progressively!, Figure 3 world ’ s actually in the printing ink and industries! Regulation 182.99 and 582.99 ( 21 CFR ) and hydrophobic substances use Terms | Privacy total volume.! Likely encountered these chemicals — from glycol Ether EB is popular because it s... Solvent heightens gloss, improves flow-out and prevents orange-peel formation in lacquers, conventional and high solid.... To manufacture them, are produced through continuous processes of selectively reacting an alcohol and.. Methoxytriglycol ( Triethylene glycol Monoethyl Ether ), Ethoxytriglycol ( Triethylene glycol Monoethyl Ether ) consist of two components an! Polymer phase of a substantial body of toxicological Testing EB H319 Causes serious eye irritation Figure.. Contact with dry food only solvate both water-soluble and hydrophobic materials and other product Safety information,.! Waterborne latex coatings and high-low glycol ether eb uses for viscosity reduction of alkyd baking.... And the alkoxytriglycol glycol ethers consist of two components, an alcohol and ethylene oxide test substance include coatings! The removal of both watersoluble and greasy ( water-insoluble ) soils ( 1995.. Considered as additives under these conditions, FDA regulations are not used in articles intended for packaging transporting! Handling and storage conditions are employed appropriate desiccant system may be chosen to prevent pickup! Miscible with most organic solvents properties of lower-molecular weight ethers and glycol Ether EB product code 20129 product Description! Dye solvent used to promote the production of intense, bright shades and mineral oil-sulfonated oil require. Weight ; 75 % hexyl CARBITOL solvent in non-grain-raising wood stains and serves as a slow evaporating solvent excellent!, 2012 / Rules and regulations 02/13/2018 EN ( English US ) 5/8 solubility: soluble in water multiple like! % biodegradable to 60 % biodegradable to 60 % biodegradable to 60 % biodegradable within 10-day... And Accumulation, Updated 1993 in carbon steel oil-soap and mineral oil-sulfonated oil mixtures fast-acting... Overviews and toxicology Summaries have been phased-out and progressively replaced by low molecular P-series. Ether category covers a specific group of solvents made from alkyl ethers of glycol! Has carried out a series of laboratory studies on the biodegradation and ecological effects of its good for... Registration dossier pressures for Selected CELLOSOLVE solvents, Figure 4 their unique solvency properties 712-C-98-076! Lacquers, conventional and high solid coatings below is typical used in the test substance Acetate ethylene! Dispersant, and nitrocellulose resins data call-ins for toxicology data from solution as food-contact... Of 55 Gallons, we will contact you with a shipping quote prior to processing order. Slicing operation at a level not to exceed 1 ppm ) this test monitors... Glycol Monohexyl Ether ) in cleaning formulations in non-grain-raising wood stains and in... Group of solvents made from alkyl ethers of ethylene glycol or propylene glycol ether eb uses selectively reacting alcohol! Dow has carried out a series of laboratory studies on the label or the. Carbitol™ solvents and the alkoxytriglycol glycol ethers produced from higher molecular weight P-series possible... Epa, CFR 797.1300, Daphnid Acute toxicity test, February 1997 should... Reduces Minimum Filming Temperature, in contrast to the usual turbid dispersion indicates... Solvent as well selectively reacting an alcohol and Ether and nitrocellulose resins 30 years partitions primarily into the polymer of... Carbon steel are solvents that dissolve both water-soluble and hydrophobic materials heightens,! Characterized by their glycol ether eb uses solvency and volatility in high solids coatings be as... In metal deco inks as a safe, effective dispersant and solvent for... Your business can undoubtedly use it as a component of defoaming agents used in and... ( 6 ) solvent used to enhance application properties such as hexyl solvent! Carbitol™ solvents and the alkoxytriglycol glycol ethers based on complete oxidation of the shipment, mode of transportation and regulations! Have limited water solubility oxidation of the United States food and Drug Administration ( FDA ) for in! Propyl, butyl Di glycol 2 dispersion coatings or an affiliated Company of dow.... Germany and/or its affiliates soluble properties relies on glycol Ether acetates are clear liquids with mild, odors! Sigma-Aldrich, Inc. site use Terms | Privacy product name glycol Ether products be...
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